Figure 1-16. (a) Structure of MOF Fe2(BDP)3; (b) Projection of a partial structure of Fe2(BDP)3, showing the chain of μ2-pyrazine-bridged iron ions; (c) Reduction of Fe2(BDP)3 with potassium naphthalenide to obtain KxFe2(BDP)3, where 0 ≤ x ≤ 2. Green spheres represent K+ sites; (d) Transient conductivity spectra of KxFe2(BDP)3 (x= 0, 0.2, 0.4, and 0.8) measured by transient microwave conductivity spectroscopy under pulsed excitation at a photon density of 6.5 × 1015 cm−2 at 355 nm; (e) Transverse voltage gating of single crystal FET devices of KxFe2(BDP)3 (x= 0, 0.19, 0.35, 0.78, 0.98, 1.35, 1.64, and 1.96) with a VSD of 1 V.

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